FUEL OILS
Fractions from crude oil distillation that are heavier than diesel/middle distillates
are often called residual fuel oils. Other commonly used names are No. 4, 5, and 6
fuel oils and bunker C. These oils can be used as fuel or as feed to refinery conver-
sion units to produce lighter, more valuable fuel fractions. The sources of fuel oils
may be directly from the distillation process and/or a complex process of selection
and blending of various petroleum fractions to meet definite specifications. In prin-
ciple, these materials start in the C
20
to C
25
range and can go higher than C
40
.
Blending with lower molecular weight fractions to decrease viscosity of heavier frac-
tions may widen the carbon range to as low as C
6
. The composition of these oils is
quite variable but they all contain saturated and aromatic hydrocarbons (including
PAHs) as well as nonhydrocarbons (heteroatom containing molecules).
There are seven different grades of fuel oil which are primarily used in different
types of fuel burning equipment under different conditions of operation. They are
grades 1& 2, grades 4 (light) and 4, grades 5 (light) and 5 (heavy), and 6. The specifi-
cations governing fuel oils are similar to those of diesel fuels with some variations.
Maximum and minimum specifications for flash point, viscosity, API gravity, ash
content, water and sediment contents, distillation end point and amount recovered,
sulfur content, cetane number, copper strip corrosion rating, aromaticity, cloud point,
and carbon residue are outlined in the standard ASTM D 396 specification for fuel oils.
LUBRICATING OILS
Lubricating oils have very high boiling points (>650°F). Typical carbon ranges are
C
20
to C
45
+. Normal paraffins (straight chain alkanes) are usually removed by
solvent extraction. These materials are enriched in cycloparaffins, aromatics, and
nonhydrocarbons and are best characterized on the basis of physical properties
such as refractive index, density, and molecular weight. They may contain 70 to
90% alkanes and 10 to 30% aromatics. Greases are lubricating oils to which a thick-
ening agent has been added. Soaps are common additives. See Table II-A-4.
Lubricating oils encompass a wide variety of commercial products used in
numerous applications. The carbon number range of a lubricating oil determines
the type of application. Refinery processes as well as the type of crude feed deter-
mine the type and quality of lubricating oil base stocks that can be used for various
applications. Lubricating oils run the gamut of products from automotive and avi-
ation oils, railroad lubricants, marine lubricants, industrial oils including turbine
oils, hydraulic oils, cylinder oils, compressor oils, refrigeration oils, and many
others too numerous to include here.
The following test specifications may be required for particular lubricating oil for-
mulations: Aniline point, ash and sulfated ash, color, ASTM D 1500, copper strip
corrosion, demulsibility, dielectric strength, flash point, fire point, API gravity, inter-
facial tension, load-carrying ability, neutralization number, oxidation stability, pour
point, cloud point, viscosity, and viscosity index. All of these tests help govern the
quality of a lubricating oil for a particular application. In some cases, the applica-
tion dictates the quality of the base stocks utilized, since functionality is a by-product
of base stock quality. ASTM D 4485 gives a summary of the specifications for the per-
formance of engine oils. Similar standards for lubricating oils are set by manufac-
turers of machinery requiring lubricants that conform to particular specifications.
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