8. EFFECT OF YIELD LOSSES ON ENERGY
The calculation of minimum energies assumed no process yield losses. However, yield losses
occur in all processes, and their effect on energy depends on where the yield loss occurs and how much
energy is "invested" in the iron or steel to that point. Some forms of yield loss have been taken into
account and the energy reclaimed in the calculation. For example, in steelmaking Fe is oxidized to the
slag, releasing energy that is used in the process. This energy release has been included in the
steelmaking energy calculation. For oxygen steelmaking, this added energy increased the hot metal
requirement and, therefore, the energy per tonne of steel. For scrap-based EAF, the "invested energy"
in the scrap was not included.
The following section addresses the impact of yield losses related to the various processes. In
all cases, the energy invested in the product is assumed to be that for the most likely case for
production. For example, for oxygen steelmaking the most likely case for production is the case for hot
metal containing silicon. The most likely case for production in the EAF is assumed to include slag and
air entrainment. A summary of the effect of yield loss on the minimum theoretical energy requirements
to produce steel is summarized in Table 8.
Ironmaking and Hot Metal Treatment
Significant yield losses can occur during tapping, handling, and treatment of hot metal. In
particular, iron is extracted with the slag during slag removal after hot metal desulfurization. Yield losses
of 1% to 3% are typical; for a 1% yield loss of liquid pig iron the energy loss would be 104 MJ. If the
iron is recovered from the slag and reused, only the sensible and melting energy (about 14 MJ) is lost.
Steelmaking
Yield losses in both oxygen steelmaking and EAF steelmaking can be significant. The highest
yield loss is FeO to the slag, which can be 5% to 10%. This yield loss releases energy, which was
considered, but more iron must be charged. Both of these effects were taken into account in the results
given for OSM and the EAF. However, there is no energy charge for the increased scrap usage.
Other yield losses can be vaporization of iron (which is oxidized to the dust), other iron losses to the
dust, and losses during tapping and handling.
Vaporization of iron consumes a considerable amount of energy in steelmaking. The energy is
not recovered when the vaporized iron is oxidized in the off gas. For 1.0% iron vaporizing in the BOF
and no energy recovery from iron oxidation, the energy loss is the energy invested in the steel (80 MJ)
and the heat of vaporization (64 MJ), or a total of 144 MJ/t of steel. Typical losses by vaporization
are about 0.5% to 1.0%. In the case of 1.0% iron vaporizing in the EAF, the invested energy in the
steel is less (13 MJ) and the total energy loss is 77 MJ.
The direct energy lost by vaporization, 64 MJ, can actually cause a larger decrease in energy
for oxygen steelmaking. The energy loss will result in less scrap melting, which will cause a shift from
scrap to hot metal. Since hot metal requires considerably more energy than melting scrap, the resulting
increase in energy could be as high as 500 MJ.
Iron is also lost to the dust by simple metal ejection. In this case, only the energy invested is
lost. Again, the iron is oxidized in the off gas and little is recovered. For a 1.0% yield
Theoretical Minimum Energies to Produce Steel for Selected Conditions 13