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Analysis of and recommendations for carbon field blank collection at Chemical
Speciation Network (CSN) sites
Recommendations
This analysis suggests that the best use of resources is to collect field blanks at a frequency of
10% at the 26 most representative 1/3 days sites and at a frequency of 20% at the 23 most
representative 1/6 day sites. This will result in lower average errors in “true” 1/3 and 1/6 day
median field blank levels at a reduced cost compared to collecting at 5% frequency at all sites.
Also, by not interpolating between months, maximum errors are much less when collecting at
field blank every month at a reduced number of sites.
Introduction and Methods
The IMPROVE and CSN networks have been considering how to best account for artifacts for
organic carbon due to the sampling on quartz fiber filters. IMPROVE has been using backup
filter concentrations to estimate artifacts and CSN has not yet adjusted organic carbon
concentrations to account for artifacts. Due mainly to the uncertainty of what the backup filter
carbon concentrations represent, the networks agreed to use field blank carbon concentrations
to account for the artifact. CSN is currently collecting field blank carbon data at all 174 sites
supported by the national laboratory contract on a 10% frequency and is considering reducing
the frequency to 5% in January 2015. This study considers the errors in network monthly
median field blank concentration by using reduced numbers of sites. Considerable cost savings
can result if number of sites collecting field blanks can be reduced. Also considered is the
collection of field blanks at 5% frequency at all sites, versus reducing the number of sites, but
keeping the frequency at 10% for one-in-three day sites and increasing to 20% at one-in-six day
sites.
CSN is also collecting backup filters for carbon analysis at all sites at a 5% frequency. Because
these data will not be used for artifact correction, they will no longer be collected. The CSN will
stop collecting carbon backup filters in January 2015. Only field blanks are considered in this
analysis.
The EPA has proposed defunding of 44 sites starting January 2015. This would leave 80 one-in-
three days and 52 one-in-six day sites under the EPA national laboratory contract. These sites
are the only sites considered in this analysis of selecting a reduced number of sites for future
carbon field blank collection.